This hotel is located quite close to the station (about 4-5 minutes), but away from the center.
It is a modern building and a good, but expensive, business-class hotel.
I have had several colleagues staying there and they were quite happy, although I would probably go for something more central.
It is about 5 minutes away from the center, but it is probably not the nicest walk you can take. I don't think it is very dangerous, but you walk through the dodgier part of Leiden (if there is such a thing).
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Address: Schipholweg 3, Leiden, Zuid-Holland, 2316 XB, The Netherlands